General Properties

The following table summarizes many of the basic physical properties of Silicon, Germanium, and Silicon Germanium at different concentrations. The concentrations are given in the form of Si1-xGex where x represents the percent composition of Germanium.

Properties

Ge

Si.25Ge.75

Si.5Ge.5

Si.75Ge.25

Si

Atoms/cm3

4.42 x 1022

Ge

*4.415 x 1022

*4.61 x 1022

*4.805 x 1022

5.0 x 1022

Si

Atomic weight

72.60

Ge

*61.4725

*50.345

*39.2175

28.09

Si

Breakdown field (V/cm)

~105

Ge

*1.5 x 105

*2 x 105

*2.5 x 105

~3 x 105

Si

Crystal Structure

Diamond

Diamond

Diamond

Diamond

Diamond

Density (g/cm3)

5.3267

Ge

*4.577

*3.827

*3.078

2.328

Si

Dielectric constant

16.0

Ge

*14.975

*13.95

*12.925

11.9

Si

Effective density of States in conduction band, Nc (cm-3)

1.04 x 1019

Ge

2.8 x 1019

Si

Effective density of States in valence band, Nv (cm-3)

6.0 x 1018

Ge

1.04 x 1019

Si

Effective Mass, m*/ m0

Electrons

Holes

m*l= 1.64

m*t= 0.082

m*l h= 0.044

m*h h= 0.28

Ge

m*l= 0.98

m*t= 0.19

m*l h= 0.16

m*h h= 0.49

Si

Electron affinity

4.0

*4.0125

*4.025

*4.0375

4.05

Properties

Ge

Si.25Ge.75

Si.5Ge.5

Si.75Ge.25

Si

Minimum Indirect Energy Gap (eV) at 300K

0.66

Ge

***0.804

***0.945

***1.05

1.12

Si

Minimum Direct Energy Gap (eV)

.7

Ge

1.6

2.5

3.1

3.4

Si

Intrinsic carrier concentration (cm-3)

2.4 x 1013

Ge

*1.8 x 1013

*1.2 x 1013

*0.6 x 1013

1.45 x 1010

Si

Intrinsic Debye length (μm)

0.68

Ge

*6.51

*12.34

*18.17

24

Si

Intrinsic resistivity

(Ω-cm)

47

Ge

*.575 x 105

*1.15 x 105

*1.725 x 105

2.3 x 105

Si

Lattice Constant (A)

***5.6575

Ge

***5.5960

***5.5373

***5.4825

***5.4310

Si

Linear coefficient of thermal expansion,

ΔL/LΔT (°C-1)

5.8 x 10-6

Ge

*5.0 x 10-6

*4.2 x 10-6

*3.4 x 10-6

2.6 x 10-6

Si

Melting point (°C)

937

Ge

*1056.5

*1176

*1295.5

1415

Si

Minority carrier

lifetime (s)

10-3

Ge

*1.375 x 10-3

*1.75 x 10-3

*2.125 x 10-3

2.5 x 10-3

Si

Mobility (drift)

(cm2/V-s)

3900(electron)

1900(hole)

Ge

*3300(electron)

*1537.5(hole)

*7700(electron)

*1175(hole)

*2100(electron)

*812.5(hole)

1500(electron)

450(hole)

Si

Optical – phonon energy (eV)

0.037

Ge

0.063

Si

Phonon mean free path

λ0(Å)

105

Ge

76 (electron)

55 (hole)

Si

Specific heat (J/g-°C)

0.31

Ge

*.4075

*.505

*.6025

0.7

Si

Thermal conductivity at 300 K (W/cm-°C)

0.6

Ge

**.11

**.083

**.085

1.5

Si

Thermal diffusivity (cm2/s)

0.36

Ge

*0.495

*.63

*.765

0.9

Si

Vapor pressure (Pa)

1 at 1330°C

10-6 at 760°C

Ge

1 at *1410°C

10-6 at *795

1 at *1490°C

10-6 at *830°C

1 at *1570°C

10-6 at *865°C

1 at 1650°C

10-6 at 900°C

Si

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